While attempting to clear following a corner, the centre-back succeeded in spectacularly half-volleying the ball past Jose Reina.
Jamie Carragher's attempted clearance richocheted in off Hyypia. But, this time, there was no way back for the Reds.
Up 1-0, and with 13 minutes left, he stuck out a leg to divert a cross into the corner of Charles Itandje's net.
The Brazilian left-back deflected in Olof Mellberg's mis-hit cross past a wrong-footed Jose Reina to give Villa a 2-1 lead with 18 minutes to go.
It was a nightmare debut for the Slovakian defender, as his deflection off Alfie Potter's shot embarrassingly put the non-League side in front for the second time.