CANBERRA/BEIJING - A CHINESE steel executive detained along with four Rio Tinto employees is under investigation for leaking China's 'bottom line' in iron ore price negotiations, a source with knowledge of the probe said on Friday.

The shock detentions have cast a shadow on relations between Beijing and Canberra, whose economies have been welded together in recent years by China's huge demand for metals and minerals.

As Australia sought to avert the diplomatic row, the China Securities Journal said Shanghai's State Security Bureau accused the three local Rio staff and senior Australian executive Stern Hu of bribing unidentified Chinese steelmakers during tense iron ore price negotiations this year.

'This seriously damaged China's economic security and interests,' said the paper, which is published by the state-run Xinhua news agency. 'The activities of Stern Hu and the others violated Chinese law as well as international business morality.'

Asked if negotiating strategy meant iron ore prices, the Reuters source said: 'Yes, China's bottom line.'

Shougang officials could not immediately be reached for comment. China's ambassador to Australia was summoned to the Foreign Ministry late on Thursday to discuss what local newspapers called a fast-escalating crisis.

A Rio spokesman expressed surprise at the turn of events, saying the group was 'not aware of any evidence that would support these allegations'.

Chinese security authorities detained the four Rio employees on Sunday, alleging they were involved in stealing state secrets. - REUTERS